L&L COATINGS CORPORATION

(813) 248-3704 or (813) 248-6723

DATE: JUNE 1996

MSDS CODE

SUPPLIER (IF OTHER THAN MANUFACTURER)

CHEMICAL DESCRIPTION: ACRYLIC ELASTOMER

PRODUCT USE: Elastomer adhesive for weather and waterproofing.

PRODUCT NAME(S) AS USED ON LABEL: #163 PRIMER/SEALER

HAZARDOUS COMPONENT

CAS NUMBER

NA/UN NUMBER

APPROX. WEIGHT %

LD50 or LC50 (species/route)

Tetrachloroisophthalonitrile

01897-45-6

Non-reg.

.277

LD50 10mg./kg. (rat/oral)

BOILING POINT (F):

Greater than 212° F

FREEZE POINT (F)

Not determined

PH

7

VAPOR PRESSURE (mmHg.)

Not available

% VOLATILE (by VOL.)

54.98%

SPECIFIC GRAVITY

1.1

VAPOR DENSITY

Not Available

EVAPORATION RATE

Slower than H₂0

SOLUBILITY IN WATER

Not Determined

ODOR THRESHOLD (ppm)

Not determined

PHYSICAL STATE

Liquid

OIL/WATER COEFFICIENT

Not determined

APPEARANCE AND ODOR: Milky fluid with faint ammonia odor

FLASH POINT (METHOD): Not applicable (water based system)

AUTO-IGNIT. TEMP.: Not applicable

LEL: Not applicable

UEL: Not applicable

SENSITIVE TO MECHANICAL IMPACT? No

TO STATIC DISCHARGE? No

FLAMMABILITY CLASSIFICATION

Product is not flammable

CONDITIONS OF FLAMMABILITY

Product is not flammable

EXTINGUISHING MEDIA

Product will not burn until most of water content has evaporated. If fire should occur after water evaporation, use water spray, carbon dioxide, dry chemical, alcohol type or universal type foams.

SPECIAL FIREFIGHTING PROCEDURES

None known

UNUSUAL FIRE AND EXPLOSION HAZARDS

Sealed product may burst open if involved in a fire due to pressure build up of steam in a closed container

HAZARDOUS COMBUSTION PRODUCTS

None known

STABLE?

YES XX

CONDITIONS OF REACTIVITY: None known

CONDITIONS OF CHEMICAL INSTABILITY: None known

INCOMPATABILITY (MATERIALS TO AVOID): None known

If fire should occur after water evaporation, carbon dioxide, carbon monoxide, oxides of nitrogen and/or trace amounts of hydrochloric acid may evolve.

NO XX

None known

ROUTES OF ENTRY

SKIN CONTACT? YES

SKIN ABSORPTION? YES

EYE CONTACT? YES

INHALATION? YES

INGESTION? YES

Tetrachloroisophthalonitrile

none available

none available

Vapor may be irritating to eyes, skin, mucous membrane, respiratory tract. Direct eye contact may cause eye irritation. No evidence of adverse effect if swallowed.

Prolonged skin contact may cause temporary reddening of skin

Inhalation: headache and nausea in poorly ventilated areas. Eye contact: stinging, redness, and tearing of eyes. Skin contact: temporary reddening of exposed areas. Swallowing: none known

Respiratory symptoms associated with pre-existing lung disease including (but not limited to) asthma, allergies, bronchitis or emphysema. Proglonged or frequent skin contact may aggravate pre-existing skin conditions such as dermatitis.

NAME OF TOXICOLOGICALLY SYNERGISTIC PRODUCTS: None known

IRRITANCY OF PRODUCT: Not determined

NO

NO

NO

NO

CARCINOGENICITY DATA: The NTP has classified tetrachloroisophthalonitrile as a carcinogen.

GLOVES (SPECIFY): Water impervious gloves during manual handling of products

EYES (SPECIFY): Safety glasses with side-shields or tight fitting goggles

FOOTWEAR (SPECIFY): Steel reinforced shoes when handling 5 gallon pails, drums or pallets

CLOTHING (SPECIFY): Long sleeves, buttoned collar, long pants extended over shoes or coveralls.

Up to 100 MG/M3: 3M Dust/Mist Mask #380, any air supplied respirator: or self-contained breathing apparatus.

ESCAPE: Any air purifying full face piece respirator with high efficiency particulate filter or any appropriate escape type self contained apparatus

Local and general ventilation in accordance with goo engineering practices should be provided to maintain airborne concentrations of vapor and spray below permissible exposure levels (PELs) specified in Section VI.

Prevent spilled materials from entering sewers, storm drains, and natural waterways. If possible, reclaim material for reuse. Otherwise, collect spill with an absorbent material into a D.O.T. approved container for disposal in an appropriate manner.

WASTE DISPOSAL PROCEDURES: Dispose in accordance with local, state and federal regulations

Keep container closed when not in use. Avoid contact with eyes. Avoid breathing spray or vapors. In accordance with good hygiene practices, the consumption of food or beverages should be avoided in the area where product is being used. After handling product, always wash hands and face thoroughly with soap and water, especially before eating and drinking.

Suitable for any general chemical storage area. Store above 40ºF to keep from freezing. Do not stack five gallon pails more than three (3) high

D.O.T. SHIP NAME : Non-regulated

D.O.T. CLASS: Non-regulated

SPECIAL SHIPPING INFORMATION: Keep from freezing

INHALATION:

No emergency care is anticipated. However, if breathing becomes difficult, remove from exposure area to fresh air immediately. If breathing has stopped give artificial respiration. Keep affected person warm and at rest. Give oxygen if respiration is shallow and get immediate medical attention.

Do not rub eyes. Wash eyes under slowly running water for at least 15 minutes, making sure eyelids are held wide open and moved slowly in every direction. Ensure no solid particles remain in creases of eyelids. If so, continue to wash. If irritation persists, consult an ophthalmologist.

Remove from source of irritation. Remove contaminated clothing and wash affected area thoroughly with a mild soap and water. Wash contaminated clothing before reusing. If irritation persists, consult a physician.

If large amounts are swallowed and person is conscious, induce vomiting to prevent further absorption. Seek immediate medical attention.

PREPARED BY: T. O. Linville

PHONE: (813)248-6723

DATE PREPARED: June 1996

ACGIH ’92; RTECS January 1993; Sax -8^th Ed.; Ind. Exposure & Control Techn. For OSHA Regulated Substances, March, 1989; NIOSH Occupational Health Guide for Chemical Substances - Vol. I & II.